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Issue 24, 1986
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Radical addition to alkene–metal cation complexes

Abstract

MP2/6–31G* calculations reveal a significant kinetic acceleration of methyl radical addition to ethylene on complexation of the alkene with the lithium cation, an effect which should be general for alkyl radical addition to alkene–metal cation complexes.

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Article information


J. Chem. Soc., Chem. Commun., 1986, 1774-1776
Article type
Paper

Radical addition to alkene–metal cation complexes

T. Clark, J. Chem. Soc., Chem. Commun., 1986, 1774
DOI: 10.1039/C39860001774

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