Kinetic resolution of β-trimethylsilyl allylic alcohols by the Sharpless process proceeds with synthetically statisfactory rate differences for the two enantiomers, thus providing a practical, effecient method for preparation of both enantiomers of erythro-epoxy secondary alcohols with high optical purity.
Y. Kitano, T. Matsumoto, Y. Takeda and F. Sato, J. Chem. Soc., Chem. Commun., 1986, 1732 DOI: 10.1039/C39860001732
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