[Pt(η2-dppmSe2)2](O3SCF3)2 decomposes by stepwise selenium extrusion via[Pt(η2-dppmSe2)(η2-dppmSe)](O3SCF3)2 to [Pt(η2-dppmSe)2](O3SCF3)2; the latter compound is also formed by the reaction of [Pt(η2-dppm)2]Cl2 and selenium or by rearrangement of [Pt(η2-dppm)(η2-dppmSe2)](O3SCF3)2[dppm = bis(diphenylphosphino)methane].
P. Peringer and J. Schwald, J. Chem. Soc., Chem. Commun., 1986, 1625 DOI: 10.1039/C39860001625
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