Issue 21, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and X-ray crystallographic characterisation of the diphosphane bridged cluster [Ir4(CO)11PhPPPhlr4(CO)9(AuPEt3)2]

J. Nicola Nicholls,   Paul R. Raithby  and  Maria D. Vargas  

Abstract

Deprotonation of [Ir4(CO)11PPhH2] followed by oxidation with Ag[ClO4] in the presence of [AuPEt3]+ affords the cluster [Ir4(CO)11PhPPPhIr4(CO)9(AuPEt3)2], which has been shown by an X-ray analysis to contain an Ir4 and an Ir4Au2 unit linked by adiphosphane (PhPPPh) ligand.

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Article information

DOI
https://doi.org/10.1039/C39860001617
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1617-1619

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Synthesis and X-ray crystallographic characterisation of the diphosphane bridged cluster [Ir4(CO)11PhPPPhlr4(CO)9(AuPEt3)2]

J. N. Nicholls, P. R. Raithby and M. D. Vargas, J. Chem. Soc., Chem. Commun., 1986, 1617 DOI: 10.1039/C39860001617

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