The electronic spectra of the salts [NiII(tim)]2+[MII(mnt)2]2–(tim = 2,3,9,10-tetramethyl-1,4,8,11-tetra-azacyclo-tetradeca-1,3,8,10-tetraene, H2mnt = 1,2-dicyano-1,2-ethylenedithiol, M2+= Ni2+, Pd2+, Pt2+) are dominated by an intense absorption band which is assigned to an outer-sphere ligand charge transfer transition from the complex anion to the cation.
A. Vogler and H. Kunkely, J. Chem. Soc., Chem. Commun., 1986, 1616 DOI: 10.1039/C39860001616
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