Issue 21, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Preparation, crystal structure, magnetic properties, and chemical reactions of a hexanuclear mixed valence manganese carboxylate

Andrew R. E. Baikie,   Andrew J. Howes,   Michael B. Hursthouse,   Andrew B. Quick  and  Peter Thornton  

Abstract

The antiferromagnetic mixed valence manganese complex [Mn6O2(Me3CCO2H)4(Me3CCO2)10] has been prepared by the reaction of MnCO3 with pivalic acid in toluene, and its molecular structure, determined by X-ray methods, comprises the new polynuclear cluster grouping of two tetrahedral oxygen-centred tetramanganeses clusters sharing an edge; further cluster complexes have been prepared by reaction of this complex with donor molecules.

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Article information

DOI
https://doi.org/10.1039/C39860001587
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1587-1587

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Preparation, crystal structure, magnetic properties, and chemical reactions of a hexanuclear mixed valence manganese carboxylate

A. R. E. Baikie, A. J. Howes, M. B. Hursthouse, A. B. Quick and P. Thornton, J. Chem. Soc., Chem. Commun., 1986, 1587 DOI: 10.1039/C39860001587

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