A novel cobalt catalyst system for the synthesis of soluble polyacetylene–polyisoprene block copolymers, via the anionic to Ziegler–Natta route is reported; preliminary experiments indicate that this catalyst is less susceptible to impurities and more versatile than the polymeric titanium catalyst route reported previously.
S. P. Armes, B. Vincent and J. W. White, J. Chem. Soc., Chem. Commun., 1986, 1525 DOI: 10.1039/C39860001525
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