Issue 20, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Novel osmium-(V) and -(IV) dioxo complexes of macrocyclic tetradentate tertiary amines: spectroscopic studies and reactivity of trans-[OsV(tmc)(O)2]+(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane)

Chi-Ming Che  and  Wing-Kin Cheng  

Abstract

trans-[OsV(tmc)(O)2]+(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) was generated by the electrochemical reduction of trans-[OsVI(tmc)(O)2]2+ in MeCN with an E½ of the OsVI/OsV couple of –0.73V vs. ferrocenium–ferrocene; the OsV complex displayed two vibronic structured d–d bands in the 300–450 nm region.

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Article information

DOI
https://doi.org/10.1039/C39860001519
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1519-1521

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Novel osmium-(V) and -(IV) dioxo complexes of macrocyclic tetradentate tertiary amines: spectroscopic studies and reactivity of trans-[OsV(tmc)(O)2]+(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane)

C. Che and W. Cheng, J. Chem. Soc., Chem. Commun., 1986, 1519 DOI: 10.1039/C39860001519

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