Catalytic aminomercuriation of 1-substituted prop-2-ynyl esters and ethers (5) provides a mild, simple, and regiospecific route to the terminal functionalized enamines (6) despite the fact that they are potentially isomerisable to their internal form; hydrolysis of (6) furnishes α-oxyketones (7).
J. Barluenga, F. Aznar, R. Liz and C. Postigo, J. Chem. Soc., Chem. Commun., 1986, 1465 DOI: 10.1039/C39860001465
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