Issue 18, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Metallo-selective substitution reactions by amines or phosphines in HRuCo3(CO)12. 1H and 59Co N.m.r. studies of HRuCo3(CO)12–xLx(L = amines or phosphines, x= 0 to 2)

Masanobu Hidai,   Hiroyuki Matsuzaka,   Yukio Koyasu  and  Yasuzo Uchida  

Abstract

The substitution of amines for the CO ligand of HRuCo3(CO)12 takes place preferentially at the ruthenium atom whereas the substitution of phosphines occurs exclusively at the cobalt atoms.

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Article information

DOI
https://doi.org/10.1039/C39860001451
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1451-1452

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Metallo-selective substitution reactions by amines or phosphines in HRuCo3(CO)12. 1H and 59Co N.m.r. studies of HRuCo3(CO)12–xLx(L = amines or phosphines, x= 0 to 2)

M. Hidai, H. Matsuzaka, Y. Koyasu and Y. Uchida, J. Chem. Soc., Chem. Commun., 1986, 1451 DOI: 10.1039/C39860001451

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