Formation of the radical cation N2H6˙+ in irradiated hydrazinium sulphate (N2H62+SO42–): an electron spin resonance study
Abstract
Exposure of [N2H62+SO42–] at 77 K to 60Co γ-rays gave SO4˙– radicals and a novel species with two equivalent nitrogen nuclei and six equivalent protons, thought to be N2H6˙+ formed by electron capture; these species readily gave NH3˙+ radicals on annealing.