Addition of halogenocarbons or dihydrogen to alkenes in the presence of [Fe2(CO)4(η-C5H5)2](1) has been shown to proceed by a non-radical catalytic cycle in which a dinuclear species, probably [Fe2(CO)3(η-C5H5)2], is the active catalyst.
R. Davis, N. M. S. Khazaal and V. Maistry, J. Chem. Soc., Chem. Commun., 1986, 1387 DOI: 10.1039/C39860001387
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