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Ruthenium and osmium tetraoxides have the same boiling point and dissolve each other to make ideal solutions, which suggests that the physical and chemical properties of these compounds are based mainly upon tetrahedrally co-ordinated oxygen atoms in the outer shell rather than the central metal ion of the molecule.
Y. Koda, J. Chem. Soc., Chem. Commun., 1986, 1347 DOI: 10.1039/C39860001347
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