Free base porphyrins with 2-anthraquinonyl and 4-dimethylaminophenyl groups attached through a sulphonyloxy link show remarkable preference for a folded conformation; introduction of zinc causes a conformational change, probably by intramolecular co-ordination.
G. M. Sanders, M. van Dijk, A. van Veldhuizen and H. C. van der Plas, J. Chem. Soc., Chem. Commun., 1986, 1311 DOI: 10.1039/C39860001311
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