Reaction of furan and thiophene with an alcohol (R–OH) at 140 °C, using a ruthenium catalyst, affords the R-alkylated dimers (2) and R,R-dialkylated trimers (3) of furan and of thiophene along with γ-keto esters (4).
R. Jaouhari, P. Guénot and P. H. Dixneuf, J. Chem. Soc., Chem. Commun., 1986, 1255 DOI: 10.1039/C39860001255
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