The first example is presented of a Diels–Alder cycloaddition of electronically neutral 2-aza-1,3-dienes using an electron-poor dienophile; the [4 + 2] cycloaddition reaction of 2-aza-1,3-dienes to heterocumulenes and carbon disulphide is also shown.
J. Barluenga, F. J. González, S. Fustero and V. Gotor, J. Chem. Soc., Chem. Commun., 1986, 1179 DOI: 10.1039/C39860001179
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