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Issue 15, 1986
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Reaction of the ylide complex [(η5-C5H5)Re(NO)(PPh3)(CH2P+Ar3)]PF6 with η-butyl-lithium–tetramethylenediamine; generation and stereospecific alkylation of a transition metal-substituted Wittig reagent

Abstract

The title reaction (tetrahydrofuran, –24 °C, 2 h) gives [(η5-C5H5)Re(NO)(PPh3)([graphic omitted]H–P+Ar3)](2; Ar =p-MeC6H4), which upon treatment with MeOSO2CF3 gives (SS,RR)-[(η5-C5H5)Re(NO)(PPh3){CH(Me)P+Ar3}]PF6[(SS,RR)-(3)] stereospecifically.

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Article type: Paper
DOI: 10.1039/C39860001154
J. Chem. Soc., Chem. Commun., 1986, 1154-1156

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    Reaction of the ylide complex [(η5-C5H5)Re(NO)(PPh3)(CH2P+Ar3)]PF6 with η-butyl-lithium–tetramethylenediamine; generation and stereospecific alkylation of a transition metal-substituted Wittig reagent

    G. L. Crocco and J. A. Gladysz, J. Chem. Soc., Chem. Commun., 1986, 1154
    DOI: 10.1039/C39860001154

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