The geometry of the title diene has been probed by X-ray crystallography and by nuclear Overhauser effect difference spectroscopy; its diastereofacial discrimination in cycloadditions is ascribed to a reacting conformation determined by the exo-anomeric effect.
R. C. Gupta, A. M. Z. Slawin, R. J. Stoodley and D. J. Williams, J. Chem. Soc., Chem. Commun., 1986, 1116 DOI: 10.1039/C39860001116
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