The photolysis of HFe(CO)4– results in the evolution of a 1 : 1 mixture of H2 and CO under Ar and assists the water gas shift reaction under 1 atm pressure of CO; a suggested mechanism involves the dinuclear reductive elimination of H2 following the photolytic extrusion of CO from HFe(CO)4–.
C. Pac, K. Miyake, T. Matsuo, S. Yanagida and H. Sakurai, J. Chem. Soc., Chem. Commun., 1986, 1115 DOI: 10.1039/C39860001115
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