Issue 14, 1986

Double aryl migration to carbon monoxide in the carbonylation of bis(mesityl)(η8-cyclo-octatetraene)zirconium(IV)

Abstract

Bis(mesityl)(η8-cyclo-octatetraene)zirconium(IV) undergoes rapid carbonylation at 0 °C to form, via migration of both mesityl (Mes) groups to carbon monoxide, [(η8-C8H8)Zr(η2-OCMes2)]2, which contains a side-on bonded diaryl ketone sharing the oxygen between two zirconium atoms.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1053-1054

Double aryl migration to carbon monoxide in the carbonylation of bis(mesityl)(η8-cyclo-octatetraene)zirconium(IV)

S. Stella and C. Floriani, J. Chem. Soc., Chem. Commun., 1986, 1053 DOI: 10.1039/C39860001053

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