(E)-Phenyl and (E)-(p-tolyl) trimethylsilyl thioketone S-oxides can be easily and stereospecifically protodesilylated into the corresponding (Z)-aryl thioaldehyde S-oxides; these stable liquid lachrimatory compounds show good reactivity as heterodienophiles and the reaction with 1,3-dienes is surprisingly non-stereospecific.
B. F. Bonini, G. Mazzanti, P. Zani, G. Maccagnani, G. Barbaro, A. Battaglia and P. Giorgianni, J. Chem. Soc., Chem. Commun., 1986, 964 DOI: 10.1039/C39860000964
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