I.r. analysis of supported CuCN reagents suggests that the active forms of these materials in nucleophilic cyanations contain the ions Cu+ and Cu(CN)2–; this is the first report of an active solid form of CuCN.
J. H. Clark, C. V. A. Duke, J. M. Miller and S. J. Brown, J. Chem. Soc., Chem. Commun., 1986, 877 DOI: 10.1039/C39860000877
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