Use of trimethylphosphine–palladium complexes renders the product-forming step in palladium-catalysed methoxycarbonylation of benzyl chloride or iodobenzene rate-determining and allows for its direct observation; the product-forming step is alcoholysis of an acylpalladium complex and not reductive elimination of a methoxycarbonylpalladium intermediate.
D. Milstein, J. Chem. Soc., Chem. Commun., 1986, 817 DOI: 10.1039/C39860000817
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