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Issue 10, 1986
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Novel insertion of [M(PR3)2] fragments (M = Pd, Pt) into the strained phosphorus–carbon bond of the phosphirene complex [W(CO)5(PhPC2Ph2)]. Crystal and molecular structure of [PtW(CO)5(PEt3)2(PhPC2Ph2)]

Abstract

The striain phosphirene ring in [W(CO)5(PhPC2Ph2)] readily undergoes insertion of [M(PR3)2] fragments (M = Pd, Pt) to give complexes in which phosphorus bridges two different metal atoms.

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Article type: Paper
DOI: 10.1039/C39860000762
J. Chem. Soc., Chem. Commun., 1986, 762-763

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    Novel insertion of [M(PR3)2] fragments (M = Pd, Pt) into the strained phosphorus–carbon bond of the phosphirene complex [W(CO)5(PhPC2Ph2)]. Crystal and molecular structure of [PtW(CO)5(PEt3)2(PhPC2Ph2)]

    D. Carmichael, P. B. Hitchcock, J. F. Nixon, F. Mathey and A. Pidcock, J. Chem. Soc., Chem. Commun., 1986, 762
    DOI: 10.1039/C39860000762

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