(-)-2,3-cis-3,3′,4′,7,8-Pentahydroxyflavanone isolated from Acacia melanoxylon represents the first example of a natural dihydroflavonol with the 2,3-cis-configuration and its identification enables a more satisfactory rationalisation to be made of the biogenesis of proanthocyanidins with the 2,3-cis-monomeric units.
L. Y. Foo, J. Chem. Soc., Chem. Commun., 1986, 675 DOI: 10.1039/C39860000675
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