Gas phase acid-induced ring-opening of an α,β-epoxysilane. The first case of complete regio- and stereo-selectivity in an ion–molecule reaction in the gas phase

P. Crotti; F. Macchia; A. Pizzabiocca; G. Renzi; M. Speranza

doi:10.1039/C39860000485

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Gas phase acid-induced ring-opening of an α,β-epoxysilane. The first case of complete regio- and stereo-selectivity in an ion–molecule reaction in the gas phase

P. Crotti, F. Macchia, A. Pizzabiocca, G. Renzi and M. Speranza

Abstract

Complete regio- and stereo-selectivity has been observed in the gas phase acid-induced ring-opening of 1,2-epoxy-1-trimethylsilycyclohexane using two different nucleophiles (i.e. H₂O and MeOH), which compares well with that of the same reaction carried out in solution.

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DOI: https://doi.org/10.1039/C39860000485
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1986, 485-487

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Gas phase acid-induced ring-opening of an α,β-epoxysilane. The first case of complete regio- and stereo-selectivity in an ion–molecule reaction in the gas phase

P. Crotti, F. Macchia, A. Pizzabiocca, G. Renzi and M. Speranza, J. Chem. Soc., Chem. Commun., 1986, 485 DOI: 10.1039/C39860000485

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Journal of the Chemical Society, Chemical Communications

Gas phase acid-induced ring-opening of an α,β-epoxysilane. The first case of complete regio- and stereo-selectivity in an ion–molecule reaction in the gas phase

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Gas phase acid-induced ring-opening of an α,β-epoxysilane. The first case of complete regio- and stereo-selectivity in an ion–molecule reaction in the gas phase

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