The stereoselective introduction of an allylic alcohol function into chiral aldehydes is readily achieved by sequential condensation of aldehydes with an allylic sulphinyl anion and thiophile-promoted desulphurization of the resulting α-substituted allylic sulphoxides.
R. Annunziata, M. Cinquini, F. Cozzi and L. Raimondi, J. Chem. Soc., Chem. Commun., 1986, 366 DOI: 10.1039/C39860000366
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