Issue 2, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

The titanium tetrachloride-mediated alkynylation and allylation of a steroidal aldehyde via stannylacetylenes and allylstannanes with high cram selectivity

Yoshinori Yamamoto,   Shinji Nishii  and  Kazuhiro Maruyama  

Abstract

The reaction of a steroidal aldehyde (1) with stannylacetylenes (2c) in the presence of TiCl4 produces the Cram isomer (3) with high diastereoselectivity.

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Article information

DOI
https://doi.org/10.1039/C39860000102
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 102-103

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The titanium tetrachloride-mediated alkynylation and allylation of a steroidal aldehyde via stannylacetylenes and allylstannanes with high cram selectivity

Y. Yamamoto, S. Nishii and K. Maruyama, J. Chem. Soc., Chem. Commun., 1986, 102 DOI: 10.1039/C39860000102

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