[(η5-C5H5)Fe(CO)(PMe3)Me], obtained from hydride reduction of [(η5-C5H5)Fe(CO)2(PMe3)]+PF6–, undergoes clean homologation on successive treatment with CO and BH3 to give after four carbonylations [(η5-C5H5)Fe(CO)(PMe3)COBun] which on oxidation yields entirely CO-derived pentanoic acid.
S. L. Brown and S. G. Davies, J. Chem. Soc., Chem. Commun., 1986, 84 DOI: 10.1039/C39860000084
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