Issue 1, 1986

Structural assignment of the dianion of 3-methylbut-2-enoic acid

Abstract

13 C N.m.r. spectra of the dianion of 3-methylbut-2-enoic acid suggest a delocalized structure; ab initio STO/3G calculations show that the only stable delocalized structure is that in which the metal lies above the plane of the molecule, as in simple allylic systems.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 50-52

Structural assignment of the dianion of 3-methylbut-2-enoic acid

A. Bongini, M. Orena and S. Sandri, J. Chem. Soc., Chem. Commun., 1986, 50 DOI: 10.1039/C39860000050

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