Bicyclotetrasilane, compared with its carbon analogue bicyclobutane, has an unusually labile central bond; the ring strain energies are comparable, but the ring separation energies opposite in sign.
T. Dabish and W. W. Schoeller, J. Chem. Soc., Chem. Commun., 1986, 896 DOI: 10.1039/C39860000896
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