The syntheses of pyrrolizidine alkaloids, (±)-trachelanthamidine, (±)-isoretronecanol, and (±)-supinidine were achieved via a carbon–carbon bond formation at the α-position to the nitrogen by employing an intramolecular carbenoid displacement (ICD) reaction as a key step.
T. Kametani, H. Yukawa and T. Honda, J. Chem. Soc., Chem. Commun., 1986, 651 DOI: 10.1039/C39860000651
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