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Issue 18, 1986
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As–as bond forming and As–C bond cleavage in the formation of [Li(thf){As(But)As(But)2}]2(thf = tetrahydrofuran). X-Ray structure of an unusual lithium organoarsenide

Abstract

[Li(thf){As(But)As(But)2}]2(thf = tetrahydrofuran), produced from the interaction of LiAs(But)2 with MgBr2(2 : 1) in thf, is a dimer with two Li atoms bridging two–As(But)As(But)2 groups and with a planar Li2As2 core [Li–As 2.58(2), As–As 2.403(2), Li ⋯ Li 3.290(3)Å].

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Article information


J. Chem. Soc., Chem. Commun., 1986, 1440-1441
Article type
Paper

As–as bond forming and As–C bond cleavage in the formation of [Li(thf){As(But)As(But)2}]2(thf = tetrahydrofuran). X-Ray structure of an unusual lithium organoarsenide

A. M. Arif, R. A. Jones and K. B. Kidd, J. Chem. Soc., Chem. Commun., 1986, 1440 DOI: 10.1039/C39860001440

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