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Issue 15, 1986
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The synthesis and characterisation, including X-ray diffraction study, of [Th{η-C5H3(SiMe3)2}3]; the first thorium(III) crystal structure

Abstract

Reduction of [ThCp″2Cl2][Cp″=η-C5H3(SiMe3)2] with Na–K in PhMe yields [ThCp″3], which is monomeric in the solid state, as determined by X-ray crystallography, and is the first crystalline tri-η-cyclopentadienylmetal complex, 〈Th–C(η-)〉 2.80(2)Å.

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Article information


J. Chem. Soc., Chem. Commun., 1986, 1148-1149
Article type
Paper

The synthesis and characterisation, including X-ray diffraction study, of [Th{η-C5H3(SiMe3)2}3]; the first thorium(III) crystal structure

P. C. Blake, M. F. Lappert, J. L. Atwood and H. Zhang, J. Chem. Soc., Chem. Commun., 1986, 1148
DOI: 10.1039/C39860001148

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