In the presence of anhydrous aluminium chloride and aluminium, chloro- and 1,1′-dichloro-ferrocenes act as moderately efficient reagents for the Friedel-Crafts arylation (i.e.‘ferrocenylation’) of simple arenes. Extensive reductive dechlorination also occurs.
P. L. Pauson, J. Šraga and Š. Toma, J. Chem. Soc., Perkin Trans. 1, 1985, 1233 DOI: 10.1039/P19850001233
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