The results of the non-linear Poisson–Boltzmann approximation for the internal energy and radial distribution functions for a charged hard-sphere model of an electrolyte are compared with Monte Carlo results. At low concentrations (≲0.05 mol dm–3) the non-linear Poisson–Boltzmann approximation is as accurate as the hypernetted-chain approximation.
D. Henderson, J. A. Barker and M. Lozada-Cassou, J. Chem. Soc., Faraday Trans. 2, 1985, 81, 457 DOI: 10.1039/F29858100457
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