Ro-vibrational lines of the 0–0 and 1–1 bands of He2(3Σ+u) have been observed by time-resolved laser intracavity absorption in the afterglow of a He discharge in the range 2–160 mbar. The metastable He2 population is made up of two coexisting and quasithermalized ensembles with a temperature difference of up to 1700 K.
B. Ståhlberg, V. M. Baev, G. Gaida, H. Schröder and P. E. Toschek, J. Chem. Soc., Faraday Trans. 2, 1985, 81, 207 DOI: 10.1039/F29858100207
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