Issue 22, 1985

Lanthanide thiolate complexes; synthesis of [Ln{N(SiMe3)2}(µ-SBut)]2(Ln = Eu, Gd, Y) and the X-ray crystal structure of the Gd complex

Abstract

The lanthanide thiolate complexes [LnL2(µ-SBut)]2[L = N(SiMe3)2; Ln = Eu, Gd, Y] have been prepared by reaction of [LnL2Cl(THF)]2(Ln = Eu, Gd; THF = tetrahydrofuran) or LnL2(THF)2(Ln = Y) with LiSBut; the crystal structure of [GdL2(µ-SBut)]2 is reported.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 1585-1586

Lanthanide thiolate complexes; synthesis of [Ln{N(SiMe3)2}(µ-SBut)]2(Ln = Eu, Gd, Y) and the X-ray crystal structure of the Gd complex

H. C. Aspinall, D. C. Bradley, M. B. Hursthouse, K. D. Sales and N. P. C. Walker, J. Chem. Soc., Chem. Commun., 1985, 1585 DOI: 10.1039/C39850001585

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