Treatment of 4-aryl-1-azido-1,3-bis(dimethylamino)-2-azabutrnylium perchlorates (5) with sodium hydroxide yields stable 6-aryl-3,5-bis(dimethylamino)-1,2,4-triazinium 1-imides (8), in which the exocyclic nitrogen atom bears only hydrogen.
G. V. Boyd, P. F. Lindley, J. C. Mitchell and G. A. Nicolaou, J. Chem. Soc., Chem. Commun., 1985, 1522 DOI: 10.1039/C39850001522
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