The synthesis of Ru(sar2+)(sar = 3,6,10,13,16,19-hexa-azabicyclo[6.6.6]icosane) from Ru(DMF)62+(DMF =N,N-dimethylformamide) and sar is described along with its properties and oxidation to Ru(sar)3+ and thence to a RuII monoimine complex.
P. Bernhard and A. M. Sargeson, J. Chem. Soc., Chem. Commun., 1985, 1516 DOI: 10.1039/C39850001516
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