Mono O-acylation of unsymmetrical diols via their dibutylstannyl derivatives takes place with high reversed chemoselectivity at the most substituted site, the reaction being complementary to standard methods.
A. Ricci, S. Roelens and A. Vannucchi, J. Chem. Soc., Chem. Commun., 1985, 1457 DOI: 10.1039/C39850001457
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