The reaction of ketene silyl acetals with arenediazonium tetrafluoroborate gave α-hydrazono and α-azo esters, which were easily hydrogenated to α-amino esters.
T. Sakakura and M. Tanaka, J. Chem. Soc., Chem. Commun., 1985, 1309 DOI: 10.1039/C39850001309
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