The complexes [Pd2X2(µ-dppm)2](1)[X = Cl, Br, I; dppm = bis(diphenylphosphino)methane] abstract sulphur from H2S under ambient conditions to form [Pd2X2(µ-S)(µ-dppm)2](2) and H2 quantitatively; (2) can be oxidized in stages to µ-SO and µ-SO2 derivatives, the latter losing SO2 spontaneously with regeneration of (1).
C. Lee, G. Besenyei, B. R. James, D. A. Nelson and M. A. Lilga, J. Chem. Soc., Chem. Commun., 1985, 1175 DOI: 10.1039/C39850001175
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...