Issue 17, 1985
From the journal:

Journal of the Chemical Society, Chemical Communications

Crystal and molecular structure of a dioxo-molybdenum phosphorus-substituted alkylidene resulting from the first observed aryl migration from molybdenum to carbon

Henri Arzoumanian,   André Baldy,   Richard Lai,   Jacques Metzger,   Marie-Louise Nkeng Peh  and  Marcel Pierrot  

Abstract

The reaction of Mo(O)2(mesityl)2 with Bu3PCH2 yields (mesityl)(O)2Mo[double bond, length half m-dash]C(mesityl)PBu3, the first example of a dioxo-metal phosphorus-substituted carbene resulting a double α-hydrogen abstraction and aryl migration from molybdenum to carbon within the co-ordination sphere of the metal.

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Article information

DOI
https://doi.org/10.1039/C39850001151
Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 1151-1152

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Crystal and molecular structure of a dioxo-molybdenum phosphorus-substituted alkylidene resulting from the first observed aryl migration from molybdenum to carbon

H. Arzoumanian, A. Baldy, R. Lai, J. Metzger, M. N. Peh and M. Pierrot, J. Chem. Soc., Chem. Commun., 1985, 1151 DOI: 10.1039/C39850001151

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