The formation of cis-3,3-dimethyl-3-silahepta-1,4-diene as the major product from addition of dimethylsilanediyl (dimethylsilylene) to cis,cis-hexa-2,4-diene is believed to result from a concerted 1,5-sigmatropic hydrogen shift in the rearrangement of the vinylsilacyclopropane intermediate formed by concerted 1,2-cis-addition of the silanediyl.
D. Lei and P. P. Gaspar, J. Chem. Soc., Chem. Commun., 1985, 1149 DOI: 10.1039/C39850001149
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