Benzonitrile and phenylacetylene undergo exclusive regio- and stereo-specific 2,6-, 2′,5′-photocycloaddition of furan: excited state interaction between the substituent and furan is considered to orient the addends and direct the reaction of this specific mode of attack.
A. Gilbert and P. Rodwell, J. Chem. Soc., Chem. Commun., 1985, 1057 DOI: 10.1039/C39850001057
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