Alkaline hydroperoxidation of a cis/trans mixture of 5,6-dimethyl-6-allylcyclohex-2-enone (4 : 1) has led to a pair of epoxides (ratio 3 :1 ) derived only from the cis isomer, whose separation was achieved chromatographically and the relative stereochemistry defined by crystal structure analysis of an ozonolysis product.
G. G. Haraldsson, L. A. Paquette and J. P. Springer, J. Chem. Soc., Chem. Commun., 1985, 1035 DOI: 10.1039/C39850001035
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