SCHEDULED MAINTENANCE
Cocondensation of rhenium vapour with 1,2,3,4,5-pentamethylcyclopentadiene gives bis(η-pentamethylcyclopentadienyl)rhenium hydride; photolysis of the hydride yields monomeric bis(η-pentamethylcyclopentadienyl)rhenium, and reduction of the latter gives a stable anion which may be readily converted into bis(η-pentamethylcyclopentadienyl)methylrhenium.
F. G. N. Cloke and J. P. Day, J. Chem. Soc., Chem. Commun., 1985, 967 DOI: 10.1039/C39850000967
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