The Al–C bond of Al(TPP)(Et)(TPP = tetraphenylporphyrinato) is homolytically cleaved upon visible light photolysis in benzene in the presence of an excess of 2,4,6-tri-t-butylnitrosobenzene, yielding spin adducts of Al(TPP) and ethyl radicals with a quantum yield of the order of 10–3.
S. Tero-Kubota, N. Hoshino, M. Kato, V. L. Goedken and T. Ito, J. Chem. Soc., Chem. Commun., 1985, 959 DOI: 10.1039/C39850000959
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