Addition of tetra-alkylthiuram disulphides [R2NC(S)S–SC(S)NR2] to MOVIS42–, WVIS42– and MOVIO2S22–yields the new complexes MoV(S2)(S2CNR2)3 and WVIS(S2)(S2CNR2)2 and the known complex MoVIO(S2)(S2CNR2)2, respectively, revealing redox behaviour involving induced internal electron transfer and lignad electron transfer processes.
W. Pan, T. R. Halbert, L. L. Hutchings and E. I. Stiefel, J. Chem. Soc., Chem. Commun., 1985, 927 DOI: 10.1039/C39850000927
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